Halide derivatives, R3SnX, often contain Sn-X-Sn bridges and form chains. Bulky R groups can affect this. For example, (SnFMe3)n has the Sn-F-Sn backbone in a zig-zag arrangement.
Tetraethyl lead produced on a huge scale as an anti-knocking agent in petrol. It can be made using Grignard's reagent. This time producing a mole of Pb:
Like alykl silicon, alkyl lead can also be made from alkyl lithiums:
Lead can also contain bridging halide atoms, if the R groups are not too bulky.
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