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Group 14

Carbon and Silicon are non-metals, Germanium a metalloid and lead a metal. The metallic character down a group is associated with:

1. Lower ionization energy, making them more willing to form cations and lose electrons into a "sea".
2. More diffuse shells, meaning less directional bonding.

Carbon and silicon have a high affinity for hard anions such as O2- and F-. The heavier group 14 elements such as lead prefer soft anions such as I- and S2-. Hardness refers to small radii, high oxidation states and low polarizability.

All group 14 elements form tetravalent hydrides (EH4, catenation (bonds between the same element) decreases down the group. This is associated with decreasing E-E bond entropy.

The largest silane (SinHn+2 chain that can form is heptasilane. Silicon's larger number of electrons means more intermolecular force. So while propane is a gas at room temperature  trisilane boils at 53 degrees.

Something called the inert-pair effect increases down the group, which results in a tendency to form +2 rather then +4.



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