The resistance of a semiconductor increases with temperature.
Superconductors have 0 resistance below a critical temperature.
It is possible to classify every type of material into these categories. Insulators, when possible to measure, are found to increase in conductivity when heated - so they can also be called semiconductors.
A-level teaches the equation:
Conductivity is the reciprocal of resistivity. A siemen (S) is defined as the reciprocal of an ohm. Using that, you should be able to tell why conductivity can use the units S cm-1.
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